Greenhouse Effect
The greenhouse effect is a natural and essential phenomenon that keeps the Earth warm enough to support life. When sunlight reaches the Earth’s surface, some of it is reflected back into space, but a significant portion is absorbed by the Earth and then re-emitted as heat (infrared radiation).
This heat doesn’t just escape into space; instead, it is trapped by greenhouse gases in the Earth’s atmosphere. These gases include:
- Water vapour
- Carbon dioxide (CO₂)
- Methane (CH₄)
- Nitrous oxide (N₂O)
- Ozone (O₃)
- Chlorofluorocarbons (CFCs) – man-made chemicals

Major Greenhouse Gases
Carbon Dioxide
- Carbon dioxide (CO₂) is the primary greenhouse gas contributing to the enhanced greenhouse effect. While CO₂ has a variety of natural sources and sinks, human activities are responsible for the considerable increase in CO₂ since the industrial revolution.
- CO₂ is part of the Earth’s carbon cycle, circulating among air, water, and ecosystems. Burning of fossil fuels (coal, oil, natural gas) and wood is the primary source of human-caused CO₂ emissions. Deforestation and land use changes reduce the effectiveness of natural sinks.
- According to the IPCC, greenhouse gas emissions have increased since the pre-industrial era, with half of all emissions since 1970.
- About 40% of emissions remain in the atmosphere, while the rest is stored in plants, soil, and oceans. Oceans absorb around 30%, but this causes ocean acidification. The future efficiency of these sinks remains uncertain.
Methane
- Methane (CH₄) is the second most important GHG after CO₂. It is emitted from both natural and human sources. Natural sources include wetlands, tundra, oceans, sediments, and termites (about 36%). Human sources (about 64%) include landfills, livestock, rice paddies, biomass burning, and fossil fuel usage.
Nitrous Oxide
- Nitrous oxide (N₂O) is the third most important GHG. Though it exists in small amounts, it has a long atmospheric lifetime (~120 years) and has nearly 300 times the global warming potential of CO₂.
- N₂O levels are now highest in 800,000 years. Since the industrial revolution, they’ve increased by 16%.
- Natural sources: soils, tundra, oceans.: Human sources: agriculture, fertilizers, manure, combustion of fossil fuels, and industrial processes.
Water Vapour
- Water vapour (H₂O) is the most abundant natural greenhouse gas. Its concentration is not directly controlled by human actions but responds to warming of the atmosphere.
- As temperatures rise, more evaporation occurs from rivers, oceans, and soil, increasing water vapour, which in turn causes more warming — a positive feedback loop crucial for climate change projections.
Ozone
Ozone (O₃) plays dual roles:
- Tropospheric ozone (ground-level): acts as a warming greenhouse gas and affects GHG lifetimes.
- Stratospheric ozone: provides a cooling effect by blocking UV radiation from the Sun.
- Tropospheric ozone is formed from pollution and sunlight, contributing to ~1/3 of GHG warming since the industrial revolution. It’s hard to track due to its short lifespan and regional variation.
- Hydroxyl (OH) radicals formed from ozone breakdown help reduce methane levels.
Synthetic Greenhouse Gases
These include long-lasting, highly potent gases like:
- CFCs (Chlorofluorocarbons)
- HCFCs (Hydrochlorofluorocarbons)
- HFCs (Hydrofluorocarbons)
- PFCs (Perfluorocarbons)
- SF₆ (Sulphur hexafluoride)
- CFCs, used in refrigerants and propellants, have a warming effect 3800x greater than CO₂ and remain in the atmosphere for over 100 years. However, international regulations have led to a decline in their concentrations.
- HFCs: used in cooling, fire protection, and foams.
- PFCs: emitted during aluminium and magnesium production, eye surgery, and uranium enrichment.
SF₆: used in power plants, switchgear, and scientific tools